Sen Wang, Zhong-Shuai Wu, Feng Zhou, Xiaoyu Shi, Shuanghao Zheng, Jieqiong Qin, Han Xiao, Chenglin Sun, Xinhe Bao
文献索引:10.1038/s41699-018-0052-8
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Planar micro-supercapacitors are recognized as one of the most competitive on-chip power sources for integrated electronics. However, most reported symmetric micro-supercapacitors suffer from low energy density. Herein, we demonstrate the facile mask-assisted fabrication of new-type all-solid-state planar hybrid micro-supercapacitors with high energy density, based on interdigital patterned films of porous vanadium nitride nanosheets as negative electrode and Co(OH)2 nanoflowers as positive electrode. The resultant planar hybrid micro-supercapacitors display high areal capacitance of 21 mF cm−2 and volumetric capacitance of 39.7 F cm−3 at 0.2 mA cm−2, and exhibit remarkable energy density of 12.4 mWh cm−3 and power density of 1750 mW cm−3, based on the whole device, outperforming most reported planar hybrid micro-supercapacitors and planar asymmetric micro-supercapacitors. Moreover, all-solid-state planar hybrid micro-supercapacitors show excellent cyclability with 84% capacitance retention after 10000 cycles, and exceptionally mechanical flexibility. Therefore, our proposed strategy for the simplified construction of planar hybrid micro-supercapacitors will offer numerous opportunities of utilizing graphene and other 2D nanosheets for high-energy microscale supercapacitors for electronics.
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