Chemistry Letters

Control of CC and CN Bond Cleavage of 2H-Azirine by Means of the Excitation Wavelength: Studies in Matrices and in Solutions.

H Inui, S Murata

文献索引：Inui, Hiroshi; Murata, Shigeru Chemistry Letters, 2001 , # 8 p. 832 - 833

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被引用次数: 11

摘要

The remarkable wavelengh-dependent photoreactions of 3-methyl-2-(1-naphthyl)-2H- azirine (1) were observed in matrices at 10 K and in solutions at room temperature. Irradiation of 1 with the long-wavelength light (366 nm) exclusively gave the products formed by the cleavage of the C–N bond of the 2H-azirine ring, while the products derived from the C–C bond cleavage were predominantly obtained in the irradiation with the short- ...