With copper and iron oxides as colorants, reddish and bluish purple glazes were prepared by changing the raw material ratio at the same firing schedule. Based on the primary factor experiments and the analyses of XRF and SEM/EDS, the fambe mechanism was proposed. The results indicated that glaze colors were related to multiple factors. The difference in copper red and purple glazes was merely caused by the later ingredient containing Ca3(PO4)2, in which liquid-liquid phase separation structures were developed and formed structural colors, while the accumulated Fe2O3 in one phase decomposed to Fe2+ and bubbles to form blue stains and colorful texture. In addition, both CuO and Fe2O3 had a variety of coloring characteristics, which depended on the process parameter, firing temperature and base glaze compositions to make colors and hues change accordingly. In such cases, the multiple chemical colors were coupled with structural colors to form the fambe glaze.