Organic letters

An Efficient Method for the Preparation of Styrene Derivatives via Rh (III)-Catalyzed Direct C–H Vinylation

KD Otley, JA Ellman

文献索引：Cao, Huanyang; Chen, Tieqiao; Zhou, Yongbo; Han, Daoqing; Yin, Shuang-Feng; Han, Li-Biao Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 765 - 769

全文：HTML全文

被引用次数: 12

摘要

... Herein, we report Rh(III)-catalyzed vinylation for the direct synthesis of styrenes without an external oxidant using vinyl ... To establish the relevance of rhodacycle 4 in catalysis, we monitored by 1 H NMR a catalytic vinylation ... This result is consistent with 4 as a catalyst resting state ...