Organic Letters

Gold-Catalyzed Intermolecular, anti-Markovnikov Hydroarylation of Methylenecyclopropanes with Indoles

JC Timmerman, WW Schmitt, RA Widenhoefer

文献索引：Scott, James S.; Gill, Adrian L.; Godfrey, Linda; Groombridge, Sam D.; Rees, Amanda; Revill, John; Schofield, Paul; Soerme, Pernilla; Stocker, Andrew; Swales, John G.; Whittamore, Paul R.O. Bioorganic and Medicinal Chemistry Letters, 2012 , vol. 22, # 21 p. 6756 - 6761

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摘要

... Table c (IPr)AuOTf employed as catalyst at 40 °C for 18 h. Table d Reaction conditions: 1a (2 mmol), 2a (2.4 mmol), and (IPr)AuOTf (4 mol %) at 40 °C for 32 h. Table e [(IPr)Au(NCPh)] + SbF 6 – employed as catalyst at 25 °C for 48 h. ...