Reduction of benzylideneacetone derivatives with Pd/SiO2-AlPO4 as catalyst and cyclohexene as hydrogen donor

…, A Aramendia, V Borau, A Garcia-Raso…

文献索引：Alba, A.; Aramendia, A.; Borau, V.; Garcia-Raso, A.; Jimenez, C.; Marinas, J. M. Canadian Journal of Chemistry, 1984 , vol. 62, p. 917 - 921

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被引用次数: 12

摘要

The hydrogen transfer reduction of benzylideneacetone derivatives pX-C6H4-CH= CH-CO- R (X=-OCH3, H; R= C6H5, alkyl, OR, OH) using cyclohexene as hydrogen donor has been studied. The selective reduction of the C= C bond is observed and the effects of the nature of X and R, solvent, catalyst, and reaction temperature on the initial reaction rate are analyzed. In all cases, and for any substrate or catalyst, the reaction is first-order with respect to the ...