The synthesis of new 60 organometallic subunits and self-assembly of three-dimensional M3L2 trigonal-bipyramidal cages

…, K Ghosh, AM Arif, PJ Stang

文献索引：Yang, Hai-Bo; Ghosh, Koushik; Arif, Atta M.; Stang, Peter J. Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9464 - 9469

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被引用次数: 27

摘要

By employing the coupling reaction of trans-PtI2 (Et3) 2 with CH bonds in alkynes as the key step, two new 60° organometallic subunits with different size from 3, 6- dibromophenanthrene were prepared in reasonable yields. The X-ray structures of both di- Pt (II) diiodide complexes showed that they were indeed suitable candidates for 60° building units. By utilizing these novel linkers as ditopic acceptor subunits, three M3L2 trigonal- ...