The Journal of Organic Chemistry

Substituted (carbazol-9-yl)(benzotriazol-1-yl) methanes: novel acyl anion equivalents

AR Katritzky, Z Yang, JN Lam

文献索引：Katritzky, Alan R.; Yang, Zhijun; Lam, Jamshed N. Journal of Organic Chemistry, 1991 , vol. 56, # 24 p. 6917 - 6923

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被引用次数: 53

摘要

Alkyl (carbazol-9-yl)(benzotriazol-l-yl) methanes are deprotonated by BuLi to form anions which react with alkyl halides, aldehydes, and isocyanates to afford the expected products and which add 1, 4 to a, b-unsaturated ketones. These products are hydrolyzed by dilute acid at ambient temperature to afford the corresponding ketones.