Organometallics

Organoboranes. 40. A simple preparation of borinic esters from organolithium reagents and selected boronic esters

HC Brown, TE Cole, M Srebnik

文献索引：Brown, Herbert C.; Cole, Thomas E.; Srebnik, Morris Organometallics, 1985 , vol. 4, p. 1788 - 1792

全文：HTML全文

被引用次数: 23

摘要

Monoorganyldiisopropoxyboranes, RB (Oi-Pr) 2, react cleanly at-78" C with 1 equiv of organolithium compounds, R'Li, to form the corresponding complexes of the borinic acid esters, LiRR'B (Oi-Pr) p. Treatment of these complexes with an equivalent of anhydrous hydrogen chloride in ethyl ether liberates the borinic esters, RR'BO-i-Pr, and isopropyl alcohol, usually readily separated by distillation. Alternatively, treatment of the complexes ...