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Ring cleavage of camphor derivatives: formation of chiral synthons for natural product synthesis

JH Hutchinson, T Money…

文献索引:Hutchinson, J. H.; Money, T.; Piper, S. E. Canadian Journal of Chemistry, 1986 , vol. 64, p. 854 - 860

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被引用次数: 38

摘要

J. H. HUTCHINSON, T. MONEY et SE PIPER. Can. J. Chem. 64,854 (1986). Sous l'action de bases, il se produit une rupture de cycle des dibromo-9,10 (ou -8,lO) camphres qui fournit des intermaiaires chiraux utiles dans la synthkse de produits naturels. ... The use of camphor as a chiral starting material in natural product synthesis (1) is dependent on the availability of methods for the regiospecific and stereoretentive functionalization of I (+)-camphor (1) or ...