The addition of halomethylene to 1, 2-dimethylcyclobutene, a methylene-olefin reaction involving a novel rearrangement

NC Yang, TA Marolewski

文献索引：Yang,N.C.; Marolewski,T.A. Journal of the American Chemical Society, 1968 , vol. 90, p. 5644 - 5646

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被引用次数: 23

摘要

33 (2: 1) a All reactions were carried out in the presence of an aqueous solution of sulfurous acid to remove the iodine formed, and the yields were calculated on the basis of polyhalomethane used. No isomerization of cis-2-butene was detected by vpc. polyiodomethane proceeds via two primary processes,(i) dissociation to form an iodine atom and a radical (reaction 1) and (ii) dissociation to form an iodine molecule and a methylene ...