Tetrahedron Letters

New ochtodane syntheses from myrcene

Y Masaki, K Hashimoto, K Kaji

文献索引：Masaki, Yukio; Hashimoto, Kinji; Sakuma, Kazuhiko; Kaji, Kenji Tetrahedron Letters, 1982 , vol. 23, # 14 p. 1481 - 1484

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被引用次数: 14

摘要

Abstract The ochtodane skeleton is formed stereoselectively from myrcene via acid- catalyzed cyclization of the benzenesulfenyl chloride adduct and that epoxide in a biogenetic type fashion. Its application to the syntheses of two ochtodane-type monoterpenes, an aldehyde component of the boll weevil pheromone and a diol found in the red alga Full-size image (< 1 K)