The action of elementary fluorine upon organic compounds. XXVI. The direct fluorination of some perfluoroalkyl-s-triazines

JB Hynes, BC Bishop, P Bandyopadhyay…

文献索引：Hynes,J.B. et al. Journal of the American Chemical Society, 1963 , vol. 85, p. 83 - 86

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被引用次数: 25

摘要

The direct vapor-phase fluorination of tris-(trifluoromethy1)-and tris-(pentafluoroethyl-s- triazines has been studied under a variety of operating conditions. When a packed T-reactor was employed, a novel substitution reaction occurred in which the perfluoroalkyl groups were progressively replaced by fluorine yielding some interesting unsymmetrical-s-triazines. The new perfluorinated secondary amines C2FjNFCiFj, CFaNFC3Fi and C3F7-NFGF, ...