The Journal of Organic Chemistry

Acetylene-allene rearrangements. Reactions of trivalent phosphorus chlorides with α-acetylenic alcohols and glycols

AP Boisselle, NA Meinhardt

文献索引：Boisselle,A.P.; Meinhardt,N.A. Journal of Organic Chemistry, 1962 , vol. 27, p. 1828 - 1833

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被引用次数: 82

摘要

The reaction of trivalent phosphorus chlorides with or-acetylenic alcohols in the presence of an organic base produced allenic, pentavalent phosphine oxides.-4 number of phosphinates and phosphonates containing both the allenic and acetylenic structures are also described for the first time. Infrared spectra of compounds of this type indicate intermolecular hydrogen bonding between the ethynyl hydrogen and the phosphoryl ...