Journal of Organometallic Chemistry

Organomagnesien reactif reducteur: VII. Mise en evidence de l'influence des interactions donneur—accepteur au cours de la reduction de benzylidenemalononitriles

D Cabaret, J Capillon, JP Guette

文献索引：Cabaret,D. et al. Journal of Organometallic Chemistry, 1976 , vol. 113, p. 215 - 224

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被引用次数: 4

摘要

Abstract The reduction of benzylidenemalononitriles by chiral aromatic organomagnesium halides and the same kind of reduction where there is no or one phenyl group gives opposite stereochemistry. These results suggest the existence of a donor—acceptor interaction between the phenyl groups in one of the transition states.