N-Alkylideneanilines. III. Behavior of N-Isopropylideneanilines in Methanol-d 4

H Iwamura, M Tsuchimoto, S Nishimura

文献索引：Iwamura,H. et al. Bulletin of the Chemical Society of Japan, 1974 , vol. 47, p. 193 - 196

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被引用次数: 3

摘要

When N-isopropylideneanilines are dissolved in methanol-d 4, three types of reactions, exchange of protons in isopropylidene moiety, formation of carbinolamine ethers, and liberation of anilines with formation of acetone dimethyl acetal take place as revealed by NMR spectra of the solutions. The H–D exchange reaction is favored by electron-releasing ring substituents and yet is considerably slower than the rates of the E–Z isomerization of ...