Uses of benzocyclopropenes in synthesis. Catalysis by silver ion

WE Billups, WY Chow, CV Smith

文献索引：Billups,W.E. et al. Journal of the American Chemical Society, 1974 , vol. 96, # 6 p. 1979 - 1980

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被引用次数: 14

摘要

CD, migration (1.061 per deuterium) and 0.970 for CD3 as the nonmigrating group (0.990 per deuterium). The isotope effect on the migrating group in the Baeyer-Villiger reaction is smaller than expected; the general trend predicts a larger per deuterium isotope effect for RCHz than for CH3. This is consistent with a smaller decrease in the HCH bending force constant or a larger increase in HCO bending force constant for benzyl migration in the ...