A New Biomimetic??Like Aromatization of the Cyclic End Groups of Terpenoids with Stereospecific Migration of One of the Methyl Groups: A Convenient Route to …

…, Z Andriamialisoa, B Valla, R Labia…

文献索引：Valla, Alain; Andriamialisoa, Zo; Valla, Benoist; Labia, Roger; Le Guillou, Regis; Dufosse, Laurent; Cartier, Dominique European Journal of Organic Chemistry, 2007 , # 4 p. 711 - 715

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被引用次数: 8

摘要

Abstract The synthesis of isorenieratene, a natural carotenoid isolated from the marine sponge Reniera japonica and from some anoxygenic phototrophic bacteria or nonphotosynthetic actinomycetes, was performed from α-, β-and retro-ionones. In this series of cyclohexenes, this synthesis is the first to include a one-pot aromatization of the cyclic end group with concomitant regioselective migration of one methyl group from the gem ...