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Reaction of nitrogen dioxide with alkenes and polyunsaturated fatty acids: addition and hydrogen-abstraction mechanisms

WA Pryor, JW Lightsey, DF Church

文献索引:Pryor, William A.; Lightsey, John W.; Church, Daniel F. Journal of the American Chemical Society, 1982 , vol. 104, # 24 p. 6685 - 6692

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被引用次数: 159

摘要

Abstract: The reactions of nitrogen dioxide in a carrier gas (nitrogen, oxygen, or air) with cyclohexene and a series of mono-, di-, and trienes is reported at NOz concentrations ranging from 70 ppm to 50%. A complete product analysis was made with cyclohexene, and these data allow the calculation of the fraction of the NOz that reacts by addition to the double bond or by abstraction of an allylic hydrogen. At high concentrations of NO2, ...