Mixed phosphine/N-heterocyclic carbene palladium complexes: synthesis, characterization and catalytic use in aqueous Suzuki–Miyaura reactions

TE Schmid, DC Jones, O Songis, O Diebolt…

文献索引：Schmid, Thibault E.; Jones, Dale C.; Songis, Olivier; Diebolt, Olivier; Furst, Marc R.L.; Slawin, Alexandra M.Z.; Cazin, Catherine S.J. Dalton Transactions, 2013 , vol. 42, # 20 p. 7345 - 7353

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被引用次数: 35

摘要

A series of N-heterocyclic carbene (NHC)/PR 3 palladium (II) and palladium (0) complexes has been synthesized and fully characterized. X-ray crystallographic data have allowed comparison of ligand steric properties. The NHC ligand was found to vary its steric properties as a function of the phosphine co-ligand. These complexes display interesting catalytic properties in the Suzuki–Miyaura reaction performed in aqueous media. The pre- ...