Migration insertion polymerization (MIP) of cyclopentadienyldicarbonyldiphenylphosphinopropyliron (FpP): a new concept for main chain metal-containing polymers ( …

X Wang, K Cao, Y Liu, B Tsang…

文献索引：Wang, Xiaosong; Cao, Kai; Liu, Yibo; Tsang, Brian; Liew, Sean Journal of the American Chemical Society, 2013 , vol. 135, # 9 p. 3399 - 3402

全文：HTML全文

被引用次数: 35

摘要

We report a conceptually new polymerization technique termed migration insertion polymerization (MIP) for main chain metal-containing polymer (MCP) synthesis. Cyclopentadienyldicarbonyldiphenylphosph... (FpP) is synthesized and polymerized via MIP, resulting in air stable poly (cyclopentadienylcarbonyldiphenylphosphin... )(PFpP) displaying narrow molecular weight distribution. The backbone of PFpP contains asymmetric iron units connected by both phosphine coordination and Fe-acyl bonds, ...