Helvetica Chimica Acta

Nucleophilic Reactions at Tertiary Carbon. Part 2. σ??and π??routes to the 8??hydrindanyl cation

KB Becker, AF Boschung, CA Grob

文献索引：Becker,K.B. et al. Helvetica Chimica Acta, 1973 , vol. 56, p. 2733 - 2747

全文：HTML全文

被引用次数: 8

摘要

Abstract Stereoisomeric ion pairs are implicated as intermediates in the solvolysis of cis and trans-8-hydrindanyl chloride 3, whereas 4-(cyclopenten-1-yl) butyl tosylate 5 appears to cyclize by way of an unsymmetrically solvated 8-hydrindanyl cation. This follows from the ...