Reactions of allylsilanes with. ALPHA.-chloro ethers catalyzed by iodotrimethylsilane or trimethylsilyl trifluoromethanesulfonate. Synthesis of homoallyl ethers.
... OR TRIMETHYLSILYL TRIFLUOROMETHANESULFONATE. SYNTHESIS OF HOMOALLYL ETHERS1) Hideki SAKURAI,* Yasuyuki SAKATA, and Akira HOSOMI Department of Chemistry, Tohoku University, Sendai 980 ... Lett., 1976, 941; (b) T. Tsunoda, M. Suzuki and R. Noyori, Tetrahedron Lett., 21, 71 (1980); (c) H. Sakurai, K. Sasaki and A. Hosomi, ibid., 22, 745 (1981). 6) Halogen-exchange reactions using a stoichiometric amount of la have been reported. ...