Achieving control over the branched/linear selectivity in palladium-catalyzed allylic amination

I Dubovyk, IDG Watson, AK Yudin

文献索引：Dubovyk, Igor; Watson, Iain D. G.; Yudin, Andrei K. Journal of Organic Chemistry, 2013 , vol. 78, # 4 p. 1559 - 1575

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被引用次数: 18

摘要

Palladium-catalyzed reaction of unsymmetrical allylic electrophiles with amines gives rise to regioisomeric allylic amines. We have found that linear products result from the thermodynamically controlled isomerization of the initially formed branched products. The ...