Tetrahedron

A convenient titanium-mediated intermolecular alkyne–carbonate coupling reaction

A Wolan, F Cadoret, Y Six

文献索引：Wolan, Andrzej; Cadoret, Frederic; Six, Yvan Tetrahedron, 2009 , vol. 65, # 36 p. 7429 - 7439

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被引用次数: 6

摘要

A direct diastereoselective titanium-mediated intermolecular coupling of internal alkynes with dialkyl carbonates under Kulinkovich-type reaction conditions is presented. The influence of the structures of the coupling partners on the yields and regioselectivities of this transformation is described.