Selenium dioxide oxidations in the indole area. Synthesis of β-carboline alkaloids

…, O Campos, F Guzman, JM Cook

文献索引：Cain, M.; Campos, O.; Guzman, F.; Cook, J.M. Journal of the American Chemical Society, 1983 , vol. 105, # 4 p. 907 - 913

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被引用次数: 54

摘要

Abstract: A number of different piperidoindole systems have been subjected to oxidation with selenium dioxide. The bonding between the indole and piperidine unit has been varied to provide different systems, the oxidation of which has led to formation of either 2-acyl-or 3- acylindoles or fully aromatic P-carbolines, depending on the substrate chosen. The pattern of reactivity observed was in complete agreement with the ene mechanism proposed for ...