Tetrahedron letters

A simple procedure for the synthesis of three-carbon homologated boronate esters and terminal alkenes via nucleopbilic displacement in α-haloallylboronate ester

HC Brown, MV Rangaishenvi

文献索引：Brown, Herbert C.; Rangaishenvi, Milind V. Tetrahedron Letters, 1990 , vol. 31, # 45 p. 7115 - 7118

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被引用次数: 20

摘要

Abstract The transfer reactions of α-haloallylboronate ester I with representative organolithium and Grignard reagents provide α-alkyl-or α-aryl-subsfituted aUylboronate esters, readily converted into three-carbon homologated boronate esters and terminal alkenes.