J. Chem. Res.(S)

Kaolin-assisted Aromatic Chlorination and Bromination

M Hirano, H Monobe, S Yakabe, T Morimoto

文献索引：Hirano, Masao; Monobe, Hiroyuki; Yakabe, Shigetaka; Morimoto, Takashi Journal of Chemical Research - Part S, 1998 , # 10 p. 662 - 663

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被引用次数: 3

摘要

Moist kaolin catalyses the regioselective and high-yielding chlorination and bromination of CHOR (R= C–C alkyl, Bu, allyl, cyclohexyl, benzyl) to 4-XCHOR (X= Cl and Br, respectively) with NaClO and Mn (acac) in CHCl in the absence and presence of NaBr, respectively, under mild and neutral conditions.