Organic letters

PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling

BH Lipshutz, S Ghorai

文献索引：Lipshutz, Bruce H.; Ghorai, Subir Organic Letters, 2009 , vol. 11, # 3 p. 705 - 708

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被引用次数: 49

摘要

The first “designer” surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.