Journal of the American Chemical Society

Diazabenzosemibullvalene. A precursor to the benzoprefulvene biradical and indenylmethylene

DP Kjell, RS Sheridan

文献索引：Kjell,D.P.; Sheridan,R.S. Journal of the American Chemical Society, 1986 , vol. 108, p. 4111

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被引用次数: 11

摘要

Abstract: Triplet-sensitized irradiation of the previously reported [4+ 21 photoadduct between naphthalene and N-methyltriazolinedione gave a di-7-methane rearranged urazole. The urazole was converted into diazabenzosemibullvalene by hydrazinolysis and oxidation. Solution thermolysis of the azo compound produced only small amounts of naphthalene, naphthvalene, benzofulvene, and mainly intractable material. Gas-phase pyrolysis gave ...