Journal of organometallic chemistry

Synthesis and Lewis acidity of triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids

MA Beckett, P Owen, KS Varma

文献索引：Beckett, Michael A.; Owen, Paul; Varma, K. Sukumar Journal of Organometallic Chemistry, 1999 , vol. 588, # 1 p. 107 - 112

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被引用次数: 31

摘要

The synthesis of 30 new triorganosilyl and triorganostannyl esters of orthoboric, metaboric, and arylboronic acids are described:(R3SiO) 3B {R3= nBuMe2, PhMe2,[2-(3-cyclohexenyl) ethyl] Me2,(nOctadecyl) Me2, nHex3};(R3MO) 3B3O3 {M= Si: R3= nPr3, nBu3, nHex3, EtMe2, nBuMe2,[2-(3-cyclohexenyl) ethyl] Me2,[(Me2HC)(Me) 2C] Me2,(nOctadecyl) Me2, PhMe2, Ph2Me, Ph3. M= Sn, R= Ph, Me};(R3MO) 2BAr {M= Si: Ar= Ph, R3= nPr3, nBu3, ...