Oxocyclopentenol syntheses

E Wenkert, RS Greenberg, MS Raju

文献索引：Wenkert, Ernest; Greenberg, Richard S.; Raju, Muppala S. Journal of Organic Chemistry, 1985 , vol. 50, # 24 p. 4681 - 4685

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被引用次数: 31

摘要

4 (Y= H) interest to discover whether the reaction scheme was applicable also to the formation of oxocyclopentenols, eg, the prostaglandin intermediate 2 (Y= OH) and tetrahydropyrethrolone (4, Y= OH). Since incorporation of a hydroxy group in the end product required the presence of an oxy substituent in the olefinic starting material at the beginning of the reaction sequence, an investigation of the behavior of a-diazo ketones ...