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537. Elimination reactions. Part I. Acid-catalysed enolisation and substitution reactions of ketones

HME Cardwell, AEH Kilner

文献索引:Cardwell; Kilner Journal of the Chemical Society, 1951 , p. 2430,2440

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被引用次数: 13

摘要

Determination of the velocities of production of the isomeric enols from a series of simple alkyl ketones has revealed that orientation of enolisation is controlled bythe ability of alkyl groups to be hyperconjugated with the developing double bond in the transition state. The