Self-replication of tris (cyanoethyl) phosphine catalysed by platinum group metal complexes
PG Pringle, MB Smith
文献索引：Costa, Emiliana; Pringle, Paul G.; Smith, Martin B.; Worboys, Kerry Journal of the Chemical Society - Dalton Transactions, 1997 , # 22 p. 4277 - 4282
The platinum (0) complex [Pt (tcep) 3], tcep= P (CH2CH2CN) 3, catalyses the formation of tcep from PH3 and CH2CHCN. The complexes [M (tcep) 3](M= Pt, Pd or Ni) and [MCl (tcep) 3](M= Rh or Ir) are compared for their catalysis of the reaction of PH (CH2CH2CN) 2 with CH2CHCN to give tcep and it is shown that the platinum (0) complex is the most efficient. The platinum (0) catalysis has been studied in detail, monitoring the kinetics by 31P-{1H} ...
