Inorganic Chemistry

Cluster syntheses. 14. The syntheses and structural characterizations of the high-nuclearity sulfidoruthenium carbonyl cluster compounds Ru5 (CO) 14 (. mu. 4-S) 2, …

RD Adams, JE Babin, M Tasi

文献索引：Adams, Richard D.; Babin, James E.; Tasi, Miklos Inorganic Chemistry, 1987 ,  vol. 26, p. 2807 - 2814            

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被引用次数: 54

摘要

The reaction of Ru,(CO),(g,-S),(2) with RU~(CO)~, under UV irradiation has yielded the higher nuclearity cluster compounds RU~(CO)~(~-CO),(~~-S)~(3), 38%, R u~(CO),~(~~- S),(4), 20%, and RU~(CO)~,(~~-S)~(5), 3%. Thermal decarbonylation of Ru3 (CO) g (p3- CO)(p3-S)(1) at 100 OC has yielded 3, 47%, 5, lo%, and RU,(CO)~~(~~-S)~(6), 26%. The large clusters are decomposed to 2 and 3 by reaction with CO at 1 atm. Compounds 4-6 ...