Macromolecules

Syntheses of biphenyl polyimides via nickel-catalyzed coupling polymerization of bis (chlorophthalimide) s

C Gao, S Zhang, L Gao, M Ding

文献索引：Gao, Changlu; Zhang, Suobo; Gao, Lianxun; Ding, Mengxian Macromolecules, 2003 , vol. 36, # 15 p. 5559 - 5565

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被引用次数: 29

摘要

A facile method for the synthesis of biphenyl polyimides, which involves the nickel-catalyzed coupling of aromatic dichlorides containing imide structure in the presence of zinc and triphenylphosphine, has been developed. The polymerizations proceeded smoothly under mild conditions and produced biphenyl polyimides with inherent viscosities of 0.13-0.98 dL/g. The polymerizations of bis (4-chlorophthalimide) s with bulky side substituents gave ...