A New Route to 1, 3-Dienes: TMSI Elimination of 2-Ene-1, 4-diols

…, K Kielbasinski, MF Baevsky, PN Nugara

文献索引：Hill, Richard K.; Pendalwar, Shekhar L.; Kielbasinski, Karen; Baevsky, Matthew F.; Nugara, Peter N. Synthetic Communications, 1990 , vol. 20, # 12 p. 1877 - 1884

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被引用次数: 7

摘要

A NEW ROUTE TO 1,3-DENES: TMSI ELIMINATION OF 2-ENE-1,4-DIOLS ... Richard K. Hill*, Shekhar L. Pendalwar, Karen Kielbasinski, Matthew F. Baevsky, and Peter N. Nugara ... Chemistry Department, School of Chemical Sciences University of Georgia, Athens, GA 30602 ... Abstract. Iodotrimethylsilane effects conversion of acyclic bis-secondary 2-ene-l,4-diols to 1,3-dienes in moderate yield. The reaction with 3-hexene-2,5-diol favors anti elimination ...