Toxic Fluorine Compounds. XVII. 1 Some 1-Fluoroalkanes, ι-Fluoroalkenes and ι-Fluoroalkynes

FLM Pattison, JJ Norman

文献索引：Pattison; Norman Journal of the American Chemical Society, 1957 , vol. 79, p. 2311,2315

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被引用次数: 27

摘要

Some 1-fluoroalkanes (n-alkyl fluorides), o-fluoroalkenes and w-fluoroalkynes were prepared for biochemical studies, and for use as intermediates in the synthesis of other compounds. Whereas no clear-cut conclusions could be drawn regarding the biochemical breakdown of 1-alkenes, evidence was obtained for o-oxidation of 1-fluoroalkanes, and, less convincingly, for hydration of 1-alkynes to the corresponding methyl ketones. Ethyl o- ...