Regioselective Hydrodebromination of Polybrominated Indoles

G Chelucci, GA Pinna, G Pinna

文献索引：Chelucci, Giorgio; Pinna, Gerard A.; Pinna, Giansalvo European Journal of Organic Chemistry, 2014 , vol. 2014, # 18 p. 3802 - 3807

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被引用次数: 0

摘要

Abstract The mixture of sodium borohydride and N, N, N′, N′-tetramethylethylenediamine in combination with a palladium catalyst is a mild and efficient system for the regioselective hydrodebromination of polybrominated indoles with both N-donating and N-withdrawing substituents [N-methyl-and N-(methoxycarbonyl) indoles, respectively].

~60%

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~97%

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~54%

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~92%

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~89%

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~98%

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~61%

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~93%

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