Journal of Organometallic Chemistry

Silicon heterocyclic compounds I. Ring size effect in ring closure by hydrosilation

JV Swisher, HH Chen

文献索引：Swisher,J.V.; Chen,H.-H. Journal of Organometallic Chemistry, 1974 , vol. 69, p. 83 - 91

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被引用次数: 29

摘要

Abstract The hydrosilation reaction has been utilized for the synthesis of silicon heterocyclic compounds. The effect of n upon the ease of ring formation from compounds of the formula CH 2 CH (CH 2) n SiMe 2 H (n= 0–6) has been investigated with chloroplatinic acid as a catalyst. No ring closure occurred when silacyclopropane and silacyclobutane were the expected products (n= 0 and 1). When n= 2, only 1, 1-dimethyl-1-silacyclopentane (46.3% ...