Unexpected reaction of 2-chloro-1-propen-3-yl isothiuronium chloride with potassium ditelluride: the first example of vicinal elimination of chlorine and sulfur-bearing …

…, LV Klyba, NV Russavskaya, OA Tarasova…

文献索引：Levanova, Ekaterina P.; Grabelnykh, Valentina A.; Elaev, Alexander V.; Albanov, Alexander I.; Klyba, Lyudmila V.; Russavskaya, Natalia V.; Tarasova, Olga A.; Rozentsveig, Igor B.; Korchevin, Nikolai A. Journal of Sulfur Chemistry, 2012 , vol. 33, # 5 p. 505 - 511,7

全文：HTML全文

被引用次数: 4

摘要

The reaction of mild nucleophiles (eg. chalcogene-containing anions) with 1,2-dihalogen derivatives of alkanes or alkenes may involve, apart from classical nucleophilic substitution, the reductive elimination of both halogen atoms in the form of halogenide anions with simultaneous oxidation of the attacking reagent. For tellurium-containing anions, the latter direction is preferable 11. Sadekov, ID; Minkin, VI Uspekh. Khim. (Russ. Chem. Rev.) 1995, 64, 527–561; Chem. ...