The Journal of Organic Chemistry

Mechanistic investigation of the oxidation of aromatic alkenes by monooxoruthenium (IV). Asymmetric alkene epoxidation by chiral monooxoruthenium (IV) complexes

WH Fung, WY Yu, CM Che

文献索引：Fung, Wai-Hong; Yu, Wing-Yiu; Che, Chi-Ming Journal of Organic Chemistry, 1998 , vol. 63, # 22 p. 7715 - 7726

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被引用次数: 84

摘要

The oxoruthenium (IV) complexes [RuIV (terpy)(6, 6'-Cl2-bpy) O](ClO4) 2 (1a; terpy= 2, 2': 6', 2''-terpyridine; 6, 6'-Cl2-bpy= 6, 6'-dichloro-2, 2'-bipyridine),[RuIV (terpy)(tmeda) O](ClO4) 2 (1b; tmeda= N, N, N', N'-tetramethylethylenediamine),[RuIV (Cn)(bpy) O](ClO4) 2 (1c; Cn= 1, 4, 7-trimethyl-1, 4, 7-triazacyclononane), and [RuIV (PPz*)(bpy) O](ClO4) 2 (1d; PPz*= 2, 6- bis [(4 S, 7 R)-7, 8, 8-trimethyl-4, 5, 6, 7-tetrahydro-4, 7-methanoindazol-2-yl] pyridine) are ...