Six dissymmetrical dihydrazide derivatives, N-(4-alkoxybenzoyl)-N′-(4′-nitrobenzoyl) hydrazine (Cn–NO2) and N-(4-alkoxybenzoyl)-N′-(4′-biphenyl carbonyl) hydrazine (Cn– Ph), were synthesized and investigated by means of differential scanning calorimetry, polarized optical microscopy and wide angle X-ray diffraction. The compounds exhibit smectic A1 phase. Based on the results of 1H NMR and variable temperature FT-IR ...