Stereoselective synthesis of allyl-C-mannosyl compounds: use of a temporary silicon connection in intramolecular allylation strategies with allylsilanes

J Beignet, J Tiernan, CH Woo…

文献索引：Pratt, Matthew R.; Leigh, Clifton D.; Bertozzi, Carolyn R. Organic Letters, 2003 , vol. 5, # 18 p. 3185 - 3188

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被引用次数: 55

摘要

... Volume: Page: ... The Journal of Organic Chemistry. ... 8a Reaction of methyl 3,4,6-tri-O-benzyl-2-O- tert-butyldimethylsilyl-α-d-mannopyranoside 17 (readily prepared from alcohol 15) with allyltrimethylsilane, in the presence of TMSOTf, provided the desired alcohol α ...