The reactions of ozone with tertiary amines including the complexing agents nitrilotriacetic acid (NTA) and ethylenediaminetetraacetic acid (EDTA) in aqueous solution

F Muñoz, C von Sonntag

文献索引：Munoz, Florinella; Von Sonntag, Clemens Journal of the Chemical Society. Perkin Transactions 2, 2000 , # 10 p. 2029 - 2033

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被引用次数: 109

摘要

Using the stopped-flow technique, the rate constants of the reaction of ozone with a number of amines have been determined. While the protonated amines do not react with ozone, the free amines react with rate constants of around 106 dm3 mol− 1 s− 1 in the case of tertiary and secondary amines, while primary amines react more slowly. Mono-protonated EDTA reacts only with k= 1.6× 105 and mono-protonated 1, 4-diazabicyclo [2.2. 2] octane ( ...