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The Journal of Organic Chemistry

Photolysis of Nitrite Esters in Solution VI. Nitroso Dimers from Alicyclic Nitrites

P Kabasakalian, ER Townley

文献索引:Kabasakalian,P.; Townley,E.R. Journal of Organic Chemistry, 1962 , vol. 27, p. 2918 - 2920

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被引用次数: 28

摘要

Discussion It is apparent from the above results that the diminution of the rate is due not to the trapping of free radicals, but instead to the formation, by the competing reductants, of a stronger intermediate complex with the active oxidizing species than that which isopropyl alcohol forms with the oxidant. The rather unusual conclusions drawn recently by Edwards6 concerning the “inhibition” of persulfate oxidations by the addition of a sequestering agent ...