Selective hydroxylation of adamantane and its derivatives

…, NA Shchadneva, LF Mukhametshina…

文献索引：Khusnutdinov; Shchadneva; Mukhametshina; Dzhemilev Russian Journal of Organic Chemistry, 2009 , vol. 45, # 8 p. 1137 - 1142

全文：HTML全文

被引用次数: 6

摘要

Abstract A general method was developed for hydroxylation into the nodal position of adamantane and its 1-and 2-substituted derivatives employing systems H 2 O-CBr 4 (BrCCl 3, CCl 4) in the presence of complexes of Pd, Ni, Ru, Co, Mo, W, and Fe. The oxidants in the systems are hypochlorous (HOCl) or hypobromous (HOBr) acids generated from water and halomethanes under the reaction conditions.