Ester aminolysis: new reaction series for the quantitative measurement of steric effects

DLF DeTar, C Delahunty

文献索引：DeTar, DeLos F.; Delahunty, Claire Journal of the American Chemical Society, 1983 , vol. 105, # 9 p. 2734 - 2739

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被引用次数: 20

摘要

Abstract: Further development of theoretical methods for computing steric effects on chemical reactivity requires a large body of new reliable quantitative data for calibration and for testing. We report here on design criteria for reaction series suitable for obtaining these data and on a successful implementation that shows promise of providing access to a particularly broad range of steric hindrance and which additionally has shown a new form ...