Mechanisms in the chlorinolysis of sulfinyl chlorides

…, MF Haley, RF Langler, JE Trenholm

文献索引：Ahern, Terence Patrick; Haley, Michael Francis; Langler, Richard Francis; Trenholm, June Ellen Canadian Journal of Chemistry, 1984 , vol. 62, p. 610 - 614

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被引用次数: 11

摘要

The successful synthesis and chlorinolysis of α-mercaptodimefhyl sulfone have provided additional support for our contention that Pummerer rearrangements may occur during the chlorinolyses of α-sulfonyl sulfinyl chlorides. Further exploration of chlorinolyses of α- sulfonyl systems has uncovered the first observations of CS bond cleavage during the chlorinolyses of (i) a sulfinyl chloride and (ii) a sulfinate ester.