High turnover remote catalytic oxygenation of alkyl groups: How steric exclusion of unbound substrate contributes to high molecular recognition selectivity

S Das, GW Brudvig, RH Crabtree

文献索引：Journal of the American Chemical Society, , vol. 130, # 5 p. 1628 - 1637

全文：HTML全文

被引用次数: 53

摘要

... Journal of the ... 2008, 130 (5), pp 1628–1637. DOI: 10.1021/ja076039m. Publication Date (Web): January 16, 2008. Copyright © 2008 American Chemical Society. ... This led us to incorporate a −CH 2 − unit next to the −COOH group to give the substrates a bent structure that was ...